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Title: Apparent Activation Energy of Coal Oxidation with Different Particle Sizes based on Temperature-programmed Approach // Proceedings of the Ninth International Seminar on Fire and Explosion Hazards. Vol. 2: 21-26 April 2019, Saint Petersburg, Russia
Creators: Zhao J. Y.; Zhang Y. X.; Deng J.; Shu C. M.; Cheng Y. C.; Yi X.
Organization: Xi’an University of Science and Technology; Shaanxi Key Laboratory of Prevention and Control of Coal Fire; Institute for Arid Ecology and Environment; National Yunlin University of Science and Technology
Imprint: Saint Petersburg, 2019
Collection: Общая коллекция
Document type: Article, report
File type: PDF
Language: English
DOI: 10.18720/SPBPU/2/k19-62
Rights: Свободный доступ из сети Интернет (чтение, печать, копирование)

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To study the effect of coal particle size on the activation energy of coal oxidation reaction in different oxidation stages, the experimental equipment of temperature-programmed tests was adopted. To determine the relationship between oxygen consumption rate and gas products, the temperature was explored in the low-temperature oxidation stage of coal samples with different particle sizes. The critical temperature point for coal samples of different particle sizes was obtained by analyzing the change rule of gas product and oxygen consumption rate with temperature, and dynamic analysis was carried out on this basis. Establishing an Arrhenius formula between the oxygen consumption rate and the coal temperature, the apparent activation energy equation was obtained from the logarithmic treatment method. The linear regression on straight line gradient of the equation was analyzed and the apparent activation energy for the low temperature oxidized coal sample was calculated. The results showed that the particle sizes affected the apparent activation energy, and the larger the particle size was, the larger the activation energy was. However, the coal samples with a particle size of 5–7 mm had the maximum apparent activation energy before the critical temperature. Compared with other particle sizes, the coal sample of this particle size did spontaneously combust easily.

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