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Оглавление
- front-matter
- Table of Contents
- Preface
- 1
- Multiscale Study of Hydrogen Storage in Metal-Organic Frameworks
- 1. Introduction
- 2. DFT study of site characteristics in MOFs for hydrogen adsorption
- 3. Grand Canonical Monte Carlo (GCMC) for gravimetric and volumetric uptakes
- Conclusion
- Reference
- 2
- Metal Organic Frameworks Based Materials for Renewable Energy Applications
- 1. Introduction
- 2. Need for renewal energy
- 3. Metal organic frameworks
- 4. MOFs for environmental applications and renewable energy
- 5. Metallic organic framework based materials for hydrogen energy applications
- 6. Hydrogen Storage by MOFs
- 7. Storage of gases and separation process by MOFs
- 8. Metal organic frameworks based materials for conversion and storage of CO2
- 9. Use of MOFs for biogas
- 10. Storage of thermal energy using MOF materials
- 11. Metal organic frameworks based materials for oxygen catalysis
- 12. MOF based materials for rechargeable batteries and supercapacitors
- 13. Metal organic framework based materials in the use of dye sensitized solar cells
- Conclusion
- References
- 3
- Metal Organic Frameworks Composites for Lithium Battery Applications
- 1. Introduction
- 2. Applications of MOFs in lithium-ion batteries
- 3. Applications of MOFs in lithium sulphur batteries.
- 4. Summary and outlook
- References
- 4
- Metal-Organic-Framework-Quantum Dots (QD@MOF) Composites
- 1. Introduction
- 1.1 Metal-organic frameworks
- 1.2 Quantum dots
- 1.3 Gold QDs (AuQDs)
- 2. QD polymeric materials
- 2.1 Integration of QDs
- 2.2 Methods of encapsulating QD to polymer matrices
- 2.3 Incorporation into premade polymers
- 2.4 Suspension polymerization
- 2.5 Encapsulation via emulsion polymerization
- 2.6 Encapsulation via miniemulsion polymerization
- 3. QD hybrid materials
- 3.1 Strategies to generate QD hybrid materials
- 3.2 Exchanging ligand between polymer and QDs
- 3.3 Polymer grafting to QDs
- 3.4 Polymer grafting from QDs
- 3.5 Polymer capping into QDs
- 3.6 QDs growth within polymer
- 3.7 Challenges in biocompatible polymer/QDs
- 4. Applications of QD composites
- 4.1 Bio-imaging
- 4.2 Photo-thermal therapies
- 4.3 Opto-electric applications
- 4.3.1 QD LEDs
- 4.3.2 Polymer QD liquid crystal displays
- 4.3.3 QD polymer photo-voltaic devices
- 5. Metallic NCs
- 5.1 Classification of metallic NCs
- 5.2 Production of metallic NCs
- 5.2.1 Metallic NCs synthesis methods
- 5.3 Applications of metallic nano-particles
- 5.3.1 Silver NCs
- 5.3.2 Pbs QDs
- Conclusion
- References
- Metal-Organic-Framework-Quantum Dots (QD@MOF) Composites
- 5
- Designing Metal-Organic-Framework for Clean Energy Applications
- 1. Introduction
- 1.1 Introduction to MOF Composites & Derivatives
- 1.2 Chemistry of MOFs
- 2. Applications of MOF in clean energy
- 2.1 Hydrogen Storage
- 2.2 Carbon dioxide capture
- 2.3 Methane storage
- 2.4 Electrical energy storage and conversion
- 2.4.1 Fuel cell
- 2.5 MOFs for supercapacitor applications
- 2.6 NH3 removal
- 2.7 Benzene removal
- 2.8 NO2 removal
- 2.9 Photocatalysis
- Conclusion
- References
- 6
- Nanoporous Metal-Organic-Framework
- 1. Introduction
- 1.1 Fundamental stabilities of nano MOFs
- 1.1.1 Chemical stability
- 1.1.2 In water medium
- 1.1.3 In acid/base condition
- 1.1.4 Thermal Stability
- 1.1.5 Mechanical Stability
- 1.2 Synthesis
- 1.2.1 Modulated synthesis
- 1.2.2 Post-synthetic modification (PSM)
- 1.3 Applications of MOFs
- 1.3.1 Gas separations and storage
- 1.3.2 Catalysis
- 1.3.2.1 Lewis acid catalysis
- 1.3.2.2 Bronsted acid catalysis
- 1.3.2.3 Redox Catalysis
- 1.3.2.4 Photocatalysis
- 1.3.2.5 Electrocatalysis
- 1.3.3 Water treatment
- 1.4 Other applications
- 1.4.1 Sensors
- 1.4.2 Supercapacitors
- 1.4.3 Biomedical applications
- Conclusion
- References
- 7
- Metal-Organic-Framework-Based Materials for Energy Applications
- 1. Introduction
- 1.1 Role of MOF in supercapacitor
- 1.2 Role of MOF in oxygen evolution reaction (OER)
- 2. Synthesis of Ni3(HITP)2 MOF
- 3. Characterization of Ni3(HITP)2 MOF
- 4. Ni3(HITP)2MOF as supercapacitor electrode for EDLC :
- 5. Two electrode measurements
- 6. Electrochemical impedance (EIS) measurements
- 7. Device performance
- 8. Hybrid Co3O4C nanowires electrode for OER process
- 9. Synthesis of hybrid Co3O4C nanowires
- 10. Characterization of hybrid Co3O4C nanowires
- 11. Hybrid Co3O4C nanowires MOF electrode for oxygen evolution reaction
- Conclusion
- References
- 8
- Metal-Organic-Framework Composites as Proficient Cathodes for Supercapacitor Applications
- 1. Introduction
- 2. MOFs: Structure, properties and strategies for SCs
- 3. Single-metal MOFs
- 4. Bimetal or doped MOFs
- 5. Hybrids and composites
- 6. Flexible or freestanding SCs
- Conclusion and Perspectives
- References
- 9
- Metal-Organic Frameworks and their Therapeutic Applications
- 1. Introduction
- 2. Metal-organic frameworks
- 2.1 Usage areas of metal-organic frameworks
- 2.1.1 Controlled drug release
- 2.1.2 Antibacterial activity of MOFs
- 2.1.3 Biomedicine
- 2.1.4 Chemical sensors
- Conclusions and recommendations
- References
- 10
- Significance of Metal Organic Frameworks Consisting of Porous Materials
- 1. Introduction
- 1.1 Definition of porosity
- 2. Inferences obtained from the wide range of relevant research articles
- 2.1 Introduction to porous MOFs
- 2.2 Zeolites – an amorphous & inorganic porous material
- 2.3 Activated carbon – an organic porous material
- 2.4 Formation of pores in MOFs
- 2.5 Types of pores
- 2.6 Characterization of porous MOFs
- 2.7 Checking for permanent porosity
- 2.8 Advantages of MOF porous materials
- 2.9 Porous MOFs in separation of gases
- 2.10 Nanoporous MOFs
- Conclusion
- References
- 11
- Metal Organic Frameworks (MOF’s) for Biosensing and Bioimaging Applications
- 1. Introduction
- 2. In vitro MOF complex sensors
- 2.1 DNA-RNA-MOF complex sensor
- 2.2 Enzyme-MOF complex
- 2.2.1 Enzymatic-MOF complex
- 2.2.2 Non-enzymatic-MOF complex
- 2.3 Fluorescent-MOF complex
- 3. In-vivo MOF complex sensors
- 3.1 MR complex
- 3.2 CT complex
- Conclusions and recommendations
- References
- 12
- Nanoscale Metal Organic Framework for Phototherapy of Cancer
- 1. Introduction
- 2. Nanoscience and nanotechnology
- 2.1 Tumor ablation and nanotechnology in cancer treatment
- 3. Metal organic frameworks (MOFs)
- 4. Photothermal therapy (PTT)
- 5. Photodynamic therapy (PDT)
- 6. Historical development of phototherapy
- 7. Mechanism of phototherapy
- 7.1 Basic elements of photodynamic therapy
- 7.1.1 Singlet oxygen
- 7.1.2 Light sources
- 8. Photosensitizers (PSs)
- 8.1 First generation photosensitizers
- 8.2 Second generation photosensitizers
- 8.3 Third generation photosensitizers
- 8.4 Introduction of tumor cells and intracellular localization of photosensitizer
- 9. Cell death in phototherapy
- 10. nMOFs for PDT
- 11. nMOFs for PTT
- 11.1 Surface plasmon resonance (SPR) mechanism and plasmonic photothermal treatment (PPTT) method
- 11.1.1 Mie theory
- 11.1.2 Gold nanostructures
- 11.1.3 Photothermal properties of different gold nanostructures
- 11.1.4 Gold nanospheres used in photothermal therapy
- 11.1.5 Gold nanocages and nanorods used in photothermal therapy
- 11.1.6 Bioconjugation of gold nanostructures used in photothermal therapy
- 11.1.7 Determination of temperature changes in gold surface
- 12. Results and Perspectives
- References
- back-matter
- Keyword Index
- About the Editors
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